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Definition

Saponification

The chemical reaction in which an alkali, either sodium hydroxide for bar soap or potassium hydroxide for liquid soap, reacts with fats and oils to form soap and glycerine.

Every oil has its own saponification value, the amount of alkali it needs, which is why a recipe cannot be scaled by weight alone and why the alkali figure must come from a proper lye calculator rather than from an estimate. This site gives planning and costing tools for soap and deliberately does not give formulation maths.

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